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Synthesis and evaluation of [105]Rhodium (III) complexes of phosphine chelate systems
(University of Missouri--Columbia, 2008)
[ACCESS RESTRICTED TO THE UNIVERSITY OF MISSOURI AT REQUEST OF AUTHOR.] [Superscript 105]RH has attractive nuclear and chemical properties to be investigated as a nuclide for development of potential radiopharmaceuticals. ...
Investigating the bifunctional chelate approach for radiopharmaceutical development
(University of Missouri--Columbia, 2010)
. Results demonstrated that in general Ga-67 conjugates had higher binding affinity, similar stability in human serum, and vast differences in both hydrophobicity and in vivo biodistribution profiles....
Determination of total selenium and seleno-amino acids in yeast and aquatic organisms by liquid chromatography and inductively coupled plasma mass spectrometry
(University of Missouri--Columbia, 2007)
-ICP-MS) was developed. Masses at 77, 78, 79, 81, and 82 were monitored and quantitation of Se was determined based on both 78Se and 82Se. SIDA-ICP-MS was successfully applied to the determination of total selenium in biological materials, such as selenized yeasts...
Method development for the analysis of nuclear forensic signatures with ICP-MS
(University of Missouri--Columbia, 2022)
Nuclear forensic analysis is a field of analytical chemistry that focuses specifically on analyzing signatures of nuclear material for criminal investigation. Promising nuclear forensic signatures include rare earths element ...
Investigation of CO2 capture systems, Lewis acid-base pairs, and oscillating reactions with electronic structure theory and kinetics-based approaches
(University of Missouri--Columbia, 2020)
Equilibrium is a key theme in chemistry education. Starting in high school and continuing in freshman general chemistry courses, STEM students have to learn the foundations of equilibria. What is the key concept of an equilibrium? How can we...
Determination and analysis of multiphoton excitation emissive species.: I,: Emission of PAHS in acidic medium,: II,: Multiphoton emission of possible PDT agents
(University of Missouri--Columbia, 2005)
[ACCESS RESTRICTED TO THE UNIVERSITY OF MISSOURI AT AUTHOR'S REQUEST.] The exploitation of ultrafast laser properties has been recently increasing. Recent research in this lab demonstrated the ability of femtosecond pulses ...
Broadband rotational spectroscopy in Laval flows: applications in astrochemistry and dynamics
(University of Missouri--Columbia, 2022)
This dissertation presents the successful implementation of a Chirped pulse Uniform Flow (CPUF) apparatus capable of conducting experiments at low temperatures to examine photodissociation/reaction dynamics and kinetics ...
Acrylate synthesis from carbon dioxide - ethylene coupling catalyzed by first-row transition metal complexes
(University of Missouri--Columbia, 2021)
Carbon dioxide (CO2) is an abundant and renewable carbon source than can be used as feedstock for the synthesis of value-added materials. One such material is acrylic acid, and acrylate derivatives, which can be used in ...
Structural supramolecular constructs of spheres and tubes
(University of Missouri--Columbia, 2006)
This thesis examines four different molecular systems that are in part or substrates for larger structural motifs that resemble spheres or tubes. The first project used donut shaped cucurbituril and through functionalization ...